Which rubber material can withstand extreme conditions?

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Kelly.C

Marketing Manager--US & EU

Rubber materials are crucial in industries that face extreme conditions. But not all rubbers are built to withstand high temperatures, aggressive chemicals, or mechanical stress. Let’s explore which rubber materials stand the test of extreme environments.

Some rubber materials, like FKM1, are specifically designed to withstand high heat and aggressive chemicals, making them essential in demanding industries.

Want to know more about rubber materials that can handle extreme conditions? Keep reading to discover which one is right for your needs.

What is FKM fluoroelastomer?

FKM, or fluoroelastomer, is a synthetic rubber made from fluorine, carbon, and hydrogen. It offers exceptional resistance to high temperatures, chemicals, and pressure.

FKM fluoroelastomer is a high-performance material known for its resistance to high heat, chemicals, and extreme pressure, making it ideal for tough environments.

a set of black rubber O-rings

FKM fluoroelastomers are often used in automotive, aerospace, and chemical industries. They are known for their ability to resist high temperatures (up to 250°C or 480°F), making them ideal for seals, gaskets, and O-rings. Additionally, FKM resists oils, fuels, solvents, and acids, which makes it highly durable in aggressive environments.

Key Benefits of FKM:

  • High Temperature Resistance: FKM can withstand up to 250°C (480°F), suitable for high-heat applications.
  • Chemical Resistance: It resists oils, solvents, acids, and fuels, making it essential in chemical processing industries.
  • Durability: FKM maintains its shape and function over time, even under extreme conditions.
Application Temperature Resistance Chemical Resistance Industry
Automotive Seals Up to 250°C Oil, fuels, solvents Automotive
Aerospace Components Up to 250°C Fuels, lubricants Aerospace
Chemical Processing Up to 250°C Acids, solvents, oils Chemical

What are the properties of FKM rubber?

FKM rubber is renowned for its superior properties like high tensile strength, excellent chemical resistance, and outstanding compression set resistance.

FKM rubber offers high resistance to heat, chemicals, and mechanical stress, which makes it perfect for seals and gaskets in extreme environments.

The properties of FKM rubber make it a top choice for industries requiring performance under extreme conditions. Its resistance to high temperatures, aggressive chemicals, and harsh mechanical forces is unparalleled. This makes FKM ideal for critical applications such as sealing and gasketing in engines, chemical tanks, and fuel systems. Additionally, FKM’s superior compression set resistance ensures that the material does not lose its sealing ability over time, even after prolonged exposure to extreme conditions.

Properties of FKM Rubber:

  • High Temperature Resistance: FKM can endure temperatures up to 250°C (480°F), ideal for heat-heavy environments.
  • Chemical Resistance: It is highly resistant to a range of chemicals, including oils, acids, and solvents.
  • Mechanical Strength: It features excellent tensile strength and resistance to compression, ensuring long-lasting performance.
Property Value
Maximum Temperature 250°C (480°F)
Chemical Resistance Oils, fuels, acids, solvents
Durability High tensile strength, excellent compression resistance

FKM is often used in automotive seals, aerospace components, and chemical processing equipment due to these unmatched properties.

Is FKM rubber better than silicone?

FKM and silicone are both used for sealing applications, but their performance under extreme conditions differs significantly.

FKM excels in high-temperature, chemical-resistant environments, while silicone is better for low-temperature flexibility and food-grade applications.

Chemical Resistance

  • FKM Rubber: Known for its superior chemical resistance, FKM can withstand exposure to strong acids, alkalis, organic solvents, and oils, making it ideal for use in corrosive environments such as the chemical and petroleum industries.

  • Silicone Rubber: While silicone is resistant to moisture and certain chemicals, it is less effective against hydrocarbon fuels and strong acids12. This limits its use in applications where chemical exposure is a concern.

Temperature Stability

  • FKM Rubber: Offers excellent high-temperature stability, capable of withstanding temperatures up to 250°C (and even higher with modifications) while maintaining elasticity and mechanical strength23. This makes it suitable for high-temperature applications like automotive engine seals.

  • Silicone Rubber: Generally performs well in a wider temperature range from -50°C to 230°C, making it suitable for cryogenic applications but less effective at extreme heat compared to FKM.

Mechanical Properties

Tensile Strength: FKM rubber has a tensile strength of about 10 MPa, significantly higher than silicone's 5 MPa, which makes FKM preferable for high-force and high-pressure applications.

Compression Set: Both materials exhibit excellent compression set properties, allowing them to maintain their shape under pressure over time.

Durability and Wear Resistance

  • FKM Rubber: Exhibits exceptional durability and resistance to wear, making it ideal for demanding environments. It also has a low coefficient of friction, which is beneficial in sealing applications.

  • Silicone Rubber: While silicone is flexible and offers good weather resistance, it tends to have poorer abrasion resistance compared to FKM, limiting its performance in dynamic applications.

Applications

  • FKM Rubber: Preferred in industries requiring strong chemical compatibility and high-temperature resilience, such as aerospace, automotive, and chemical processing.

  • Silicone Rubber: More commonly used in applications involving food-grade materials, medical devices, and environments where flexibility at low temperatures is crucial.

Property FKM Rubber Silicone Rubber
Chemical Composition Special synthetic rubber material Silicone rubber
Temperature Resistance -20°C to 250°C (up to 300°C with additives) -50°C to 230°C (better for cryogenic)
Tensile Strength Approx. 10 MPa Approx. 5 MPa
Abrasion Resistance Fair to good Poor
Chemical Compatibility Resistant to acids, alcohols, fuels, oils Compatible with oils, brake fluids, water
Incompatibility Not compatible with amines and some solvents Not compatible with hydrocarbon fuels and strong acids
Weather Resistance Excellent Excellent
Compression Set Excellent Excellent
Applications High-pressure seals in automotive and chemical industries High-temperature applications, food-grade uses

FKM rubber generally offers better performance in terms of chemical resistance, temperature stability, tensile strength, and durability compared to silicone rubber.

However, the choice between the two materials ultimately depends on the specific requirements of the application. For high-stress environments with exposure to chemicals and extreme temperatures, FKM is often the superior choice. Conversely, for applications that prioritize flexibility and lower temperature performance, silicone may be more appropriate.

Is fluoroelastomer expensive?

Fluoroelastomers2 like FKM are more expensive than other rubber materials due to their superior properties and complex manufacturing process.

While FKM is a high-cost material, its exceptional durability and resistance make it worthwhile for industries that need performance in extreme environments.

a collection of various washers and gaskets

Fluoroelastomers like FKM are generally more expensive than standard rubber materials due to the high cost of their raw materials and the complex manufacturing processes required to create them. However, for industries where reliability, heat resistance, and chemical resistance are critical, the higher cost is justified by the material’s long lifespan and superior performance. This means fewer replacements, less downtime, and lower long-term costs for industries that require materials that can handle extreme conditions.

Why Fluoroelastomers Are Expensive:

  • Raw Materials: Fluorine-based chemicals are costly, making FKM production expensive.
  • Manufacturing Process: The production of fluoroelastomers involves complex processes that drive up the cost.
  • Long-term Cost Savings: Although FKM is more expensive upfront, its durability reduces the need for frequent replacements.
Factor Reason for High Cost
Raw Material Fluorine-based chemicals are expensive
Manufacturing Process Specialized processes increase costs
Durability Longer lifespan reduces total cost of ownership

Despite the higher price, the durability and resistance to extreme conditions make FKM a preferred material for critical applications.

Conclusion

FKM,fluoroelastomer is a top choice for extreme conditions, offering unmatched heat, chemical, and mechanical resistance, though it comes at a higher price.

Footnotes:


  1. FKM is a type of fluoroelastomer, commonly used in industries where heat and chemical resistance are crucial. 

  2. Fluoroelastomers are more costly but offer long-term durability and exceptional resistance to extreme conditions. 

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