It resists oil like plastic. It flexes like rubber. So is fluoroelastomer a rubber—or a plastic with rubbery behavior?
Fluoroelastomer is a synthetic rubber, not a plastic. It belongs to a class of flexible, high-performance elastomers designed for sealing in harsh environments.
I’ve had many clients ask this when comparing it to PTFE (Teflon®). They’re both fluorinated—but only one stretches and seals under compression. That one is fluoroelastomer.
What is fluoroelastomer made of?
Fluoroelastomer isn’t just rubber—it’s engineered for survival. Its backbone chemistry is what gives it extreme durability against heat, oils, and chemicals.
Fluoroelastomer is made from fluorinated monomers such as vinylidene fluoride (VDF), hexafluoropropylene (HFP), tetrafluoroethylene (TFE), and sometimes perfluoromethylvinyl ether (PMVE).
🧪 Typical FKM Polymer Types
FKM Type | Main Monomers | Features |
---|---|---|
Type A | VDF + HFP1 | Standard oil/fuel resistance |
Type B | VDF + HFP + TFE | Improved chemical resistance2 |
Type F | VDF + HFP + TFE + PMVE | Base and steam resistance |
FEPM | Perfluorinated monomers | Extreme chemical and amine resistance |
These monomers are polymerized and vulcanized into rubber sheets, O-rings, or custom-molded seals. Once cured, the material becomes a non-melting, elastic sealing compound ready for industrial use.
What makes fluoroelastomer a rubber?
Rubbers, or elastomers, are polymers that can stretch and return to shape. Plastics, on the other hand, tend to be rigid and non-elastic.
Fluoroelastomer (FKM) behaves like a traditional rubber—it’s compressible, flexible, and seals effectively under pressure.
🛠️ Characteristics of Fluoroelastomer Rubber3
Feature | Behavior |
---|---|
Flexibility | Elastic—can stretch and compress |
Shore A hardness | Typically 60–90 (like standard rubber) |
Sealing method | Compression in grooves or housings |
Heat/chemical resistance | Exceptional among rubbers |
Appearance | Matte finish, slightly tacky or dry feel |
We use FKM in applications that require long-term sealing with flexibility—like O-rings, shaft seals, and gaskets4. It fits tightly into grooves and holds its shape without permanent deformation.
Why do people confuse fluoroelastomer with plastic?
Because it’s related to PTFE and other fluoroplastics—and because it’s often found in harsh environments where plastics are also used.
Fluoroelastomer and PTFE share similar chemical resistance, but PTFE is a rigid thermoplastic, while FKM is a flexible rubber elastomer.
🔍 Rubber vs Plastic Comparison
Property | Fluoroelastomer (FKM)5 | Fluoroplastic (PTFE)6 |
---|---|---|
Flexibility | ✅ Yes | ❌ No |
Compressibility7 | ✅ Yes | ❌ Very limited |
Sealing method | Compression sealing | Machined fit/seating |
Recovery after deflection | ✅ Good | ❌ Poor |
Melting point | No melt (vulcanized rubber) | Melts at ~327°C |
If you need something that bends, seals dynamically, and can be molded into rubber shapes—FKM is your answer. If you need a rigid liner or dry-lubricated contact, PTFE makes more sense.
Where does this matter in real applications?
In chemical pumps, fuel injectors, and valve systems, material behavior under load determines sealing success.
Fluoroelastomer seals conform to imperfect surfaces, recover from dynamic motion, and hold pressure. Plastics can’t.
📌 What FKM Can Do That Plastic Can’t
Action | FKM Response | Plastic Response |
---|---|---|
Groove compression | Compresses and fills gaps | Stays rigid, leaks likely |
Shaft motion | Lip flexes and reseals | No flex—wear or failure |
Long-term stress | Maintains elastic rebound | May creep, crack, or flatten |
Assembly ease | Snaps into grooves easily | Needs precise machining |
I’ve seen projects where clients tried PTFE washers as gaskets—only to replace them months later with FKM for long-term success.
Does fluoroelastomer have PFAS in it?
Yes—fluoroelastomer contains fluorine-based chemicals that fall under the broad definition of PFAS (per- and polyfluoroalkyl substances).
All fluoroelastomers are considered part of the PFAS family because they contain multiple carbon-fluorine bonds, which are extremely stable and persistent in the environment.
⚠️ What You Should Know
Aspect | FKM Reality |
---|---|
Contains C–F bonds | ✅ Yes—by design |
Classified as PFAS8 | ✅ Under EPA and EU definitions |
Risk of leaching | ⚠️ Very low in cured rubber form |
Regulatory scrutiny | ✅ Increasing (especially in EU/US markets) |
At Julong, we monitor PFAS-related regulations closely. While FKM is not banned, its use may be restricted in the future for food, medical, or drinking water systems in certain countries. For sensitive sectors, we can suggest alternative materials like EPDM or silicone where appropriate.
FKM remains safe and effective for industrial and automotive use. But if your product is subject to PFAS disclosure or sustainability audits, you should confirm the impact of using fluoroelastomer in your system.
Conclusion
Fluoroelastomer is rubber—chemically advanced, but mechanically elastic. It’s not a plastic, and it’s not rigid. It stretches, seals, and survives where other rubbers fail.
Need flexible, chemical-resistant rubber seals?
Contact Julong Rubber or Request a Quote for molded or extruded FKM parts.
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Exploring this link will provide insights into the practical uses and benefits of VDF + HFP in various industrial applications. ↩
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Understanding chemical resistance is crucial for selecting the right sealing materials, ensuring durability and performance in challenging environments. ↩
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Explore this link to understand the diverse applications of Fluoroelastomer Rubber, especially in sealing solutions. ↩
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Learn about the advantages of O-rings, shaft seals, and gaskets, and how they enhance performance in various applications. ↩
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Explore the benefits of FKM to understand its applications in various industries, enhancing your knowledge on material selection. ↩
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Learn about PTFE's unique properties and applications, which can help you make informed decisions for your projects. ↩
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Understanding compressibility can significantly impact your material choices, ensuring optimal performance in engineering applications. ↩
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Understanding PFAS regulations is crucial for compliance and safety in sensitive sectors. Explore this link for the latest updates. ↩